| Monday, 4 February 1991 | Ann Hampton Callaway |
| Tuesday, 19 March 1991 | George Michael |
| Thursday, 4 April 1991 | Rod Stewart |
| Tuesday, 16 April 1991 | The Alarm |
| Friday, 26 April 1991 | Jimmy Somerville |
| Tuesday, 14 May 1991 | Jack Dee Up West (Channel 4 TV Recording) |
| Sunday, 9 June 1991 | Pet Shop Boys |
| Sunday, 21 July 1991 | Morrissey |
| Tuesday, 29 October 1991 | Kylie Minogue |
| Thursday, 14 November 1991 | Diana Ross |
| Thursday, 19 December 1991 | Paul Young |
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