| Thursday, 19 January 2012 | Smooth Radio Ones To Watch 2012 |
| Friday, 9 March 2012 | Judie Tzuke |
| Tuesday, 20 March 2012 | Two Choirs - One Messiah |
| Thursday, 26 April 2012 | Mike Sealy & Friends |
| Friday, 1 June 2012 | Coldplay |
| Saturday, 14 July 2012 | Bruce Springsteen & The E Street Band |
| Tuesday, 17 July 2012 | Paloma Faith |
| Sunday, 7 October 2012 | Barbara Costa & Emanuele Delucchi |
| Saturday, 17 November 2012 | Andy Fairweather-Low & The Low Riders |
| Sunday, 2 December 2012 | Elbow |
| Wednesday, 19 December 2012 | Smooth Radio Love Live Music at Christmas |
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